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- <meta content="Canty, A.J." name="eprints.creators_name" />
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- <meta content="Stable organopalladium(IV) complexes [fac-PdMe3(L)]1 (L = tridentate nitrogen donor ligand) are formed on
- oxidative addition of iodomethane to PdMe2(L); the tris(pyrazo1-1-yl)methane complex is isostructural with the
- platinum(IV) analogue." name="eprints.abstract" />
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- <meta content="1 W. J. Pope and S. J. Peachey, Proc. Chem. Soc., 1907, 23, 86;
- J . Chem. SOC., 1909, 571.
- 2 P. M. Maitlis, P. Espinet, and M. J. H. Russell, in 'Comprehensive
- Organometallic Chemistry,' eds. G. Wilkinson, F. G. A. Stone,
- and E. W. Abel, Pergamon Press, New York, 1982, vol. 6,
- 3 e.g., R. F. Heck, 'Palladium Reagents in Organic Syntheses,'
- Academic Press, London, 1985; B. M. Trost, in ref. 2, vol. 8,
- 4 P. M. Maitlis, 'The Organic Chemistry of Palladium,' Academic
- 5 P. M. Henry, Adv. Organomet. Chem., 1975, 13, 363.
- 6 T. Ito, H. Tsuchiya, and A. Yamamoto, Bull. Chem. Sac. Jpn.,
- 1977, 50, 1319; F. Ozawa, K. Kurihara, T. Yamamoto, and A.
- Yamamoto, ibid., 1985, 58, 399.
- 7 J. K. Stille and K. S. Y. Lau, J. Am. Chem. SOC., 1976,98,5841;
- D. Milstein and J. K. Stille, ibid., 1979, 101,4981,4992; A. Gillie
- and J. K. Stille, ibid., 1980, 102,4933; M. K. Loar andJ. K. Stille,
- ibid., 1981, 103, 4174; A. Moravskiy and J. K. Stille, ibid., 1981,
- 103, 4182.
- 8 P. Diversi, D. Fasce, and R. Santini, J. Organomet. Chem., 1984,
- 269, 285.
- 9 H. Kurosawa, M. Emoto, and A. Urabe, J. Chem. Soc., Chern.
- Commun., 1984, 968.
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- Met.-Org. Chem., 1977, 7, 235; J. Organomet. Chem., 1975, 96,
- 307.
- 11 P. K. Byers, A. J. Canty, B. W. Skelton, and A. H. White,
- J. Chem. SOC., Chem. Commun., 1986, 1722.
- 12 A. J. Canty and R. T. Honeyman, unpublished results.
- 13 K. I. ThC and L. K. Peterson, Can. J. Chem., 1973, 51, 422.
- 14 P. K. Byers and A. J. Canty, Znorg. Chim. Acta, 1985, 104, L13.
- 15 A. J. Canty, R. T. Honeyman, B. W. Skelton, and A. H. White,
- 16 J. M. Wisner, T. J. Bartczak, and J. A. Ibers, Organometallics,
- 17 H. C. Clark, G. Ferguson, V. K. Jain, and M. Parvez,
- 18 P. K. Byers, A. J. Canty, L. M. Engelhardt, and A. H. White,
- pp. 339-340.
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- Press, 1971, vol. 1, pp. 83-84.
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- J. Chem. SOC., Dalton Trans., 1986, 1731." name="eprints.referencetext" />
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- <h1 class="ep_tm_pagetitle">Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I</h1>
- <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Byers, P.K.</span> and <span class="person_name">Canty, A.J.</span> and <span class="person_name">Skelton, B.W.</span> and <span class="person_name">White, A.H.</span> (1987) <xhtml:em>Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I.</xhtml:em> Chemical Communications . pp. 1093-1095. ISSN 1359-7345</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2859/1/CC1987_2C_1093.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" class="ep_doc_icon" border="0" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2859/1/CC1987_2C_1093.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />329Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input accept-charset="utf-8" value="4079" name="docid" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://dx.doi.org/10.1039/C39870001093">http://dx.doi.org/10.1039/C39870001093</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">Stable organopalladium(IV) complexes [fac-PdMe3(L)]1 (L = tridentate nitrogen donor ligand) are formed on
- oxidative addition of iodomethane to PdMe2(L); the tris(pyrazo1-1-yl)methane complex is isostructural with the
- platinum(IV) analogue.</p></div><table style="margin-bottom: 1em" cellpadding="3" class="not_ep_block" border="0"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences > 259900 Other Chemical Sciences > 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2859</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">14 Jan 2008 11:35</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">14 Jan 2008 11:35</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2859;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&eprintid=2859">item control page</a></p>
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